a recipe asks for vinegar earlier, follow that method because simmering changes how the acidity and aroma feel. Taste again after the vinegar is fully mixed in.
Remember that other ingredients bring acidity too. Lemon, yogurt, tomatoes, pickles and hot sauce can already be doing that job. A meal containing several of them may need no additional vinegar at all.
Keep a simple finishing routine
For a bean salad, mix the dressing separately and coat the beans gradually. For soup, test a small splash in a single serving before adjusting the pot. For roasted vegetables, toss lightly and serve while
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